The most expensive colognes for men include luxurious options like Shumukh by Nabeel priced at $1.29 million, which features rare ingredients such as pure Turkish rose, Indian agarwood, and is housed in a crystal bottle adorned with gold and diamonds. Other highly priced colognes include Gianni Vive Sulman Parfum VI at $89,000, Amaffi Power for Men at $7,100, Roja Haute Luxe by Roja Parfums at $3,500, and Tom Ford's Myrrhe Mystère Eau de Parfum at $1,350. These colognes command their high prices due to rare ingredients like oud, extensive craftsmanship, limited editions, and luxurious packaging often featuring precious materials and jewels.